Browsing by Author "Breuer, Lutz"
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Item Addressing sources of uncertainty in runoff projections for a data scarce catchment in the Ecuadorian Andes(2014) Exbrayat, Jean Francois; Buytaert, Wouter; Timbe Castro, Edison Patricio; Windhorst, David; Breuer, LutzFuture climate projections from general circulation models (GCMs) predict an acceleration of the global hydrological cycle throughout the 21st century in response to human-induced rise in temperatures. However, projections of GCMs are too coarse in resolution to be used in local studies of climate change impacts. To cope with this problem, downscaling methods have been developed that transform climate projections into high resolution datasets to drive impact models such as rainfall-runoff models. Generally, the range of changes simulated by different GCMs is considered to be the major source of variability in the results of such studies. However, the cascade of uncertainty in runoff projections is further elongated by differences between impact models, especially where robust calibration is hampered by the scarcity of data. Here, we address the relative importance of these different sources of uncertainty in a poorly monitored headwater catchment of the Ecuadorian Andes. Therefore, we force 7 hydrological models with downscaled outputs of 8 GCMs driven by the A1B and A2 emission scenarios over the 21st century. Results indicate a likely increase in annual runoff by 2100 with a large variability between the different combinations of a climate model with a hydrological model. Differences between GCM projections introduce a gradually increasing relative uncertainty throughout the 21st century. Meanwhile, structural differences between applied hydrological models still contribute to a third of the total uncertainty in late 21st century runoff projections and differences between the two emission scenarios are marginal.Item Assessment of hydrological pathways in East African montane catchments under different land use(2018) Jacobs, Suzanne R.; Rufino, Mariana; Butterbach Bahl, Klaus; Timbe Castro, Edison Patricio; Weeser, Bjorn; Breuer, LutzConversion of natural forest (NF) to other land uses could lead to significant changes in catchment hydrology, but the nature of these changes has been insufficiently investigated in tropical montane catchments, especially in Africa. To address this knowledge gap, we aimed to identify stream water (RV) sources and flow paths in three tropical montane sub-catchments (27–36 km2 ) with different land use (natural forest, NF; smallholder agriculture, SHA; and commercial tea and tree plantations, TTP) within a 1021 km2 catchment in the Mau Forest complex, Kenya. Weekly samples were collected from stream water, precipitation (PC) and mobile soil water for 75 weeks and analysed for stable isotopes of water (δ2H and δ18O) for mean transit time (MTT) estimation with two lumped parameter models (gamma model, GM; and exponential piston flow model, EPM) and for the calculation of the young water fraction. Weekly samples from stream water and potential endmembers were collected over a period of 55 weeks and analysed for Li, Na, Mg, K, Rb, Sr and Ba for endmember mixing analysis (EMMA). Solute concentrations in precipitation were lower than in stream water in all catchments (p < 0.05), whereas concentrations in springs, shallow wells and wetlands were generally more similar to stream water. The stream water isotope signal was considerably damped compared to the isotope signal in precipitation. Mean transit time analysis suggested long transit times for stream water (up to 4 years) in the three sub-catchments, but model efficiencies were very low. The young water fraction ranged from 13 % in the smallholder agriculture sub-catchment to 15 % in the tea plantation sub-catchment. Mean transit times of mobile soil water ranged from 3.2–3.3 weeks in forest soils and 4.5–7.9 weeks in pasture soils at 15 cm depth to 10.4–10.8 weeks in pasture soils at 50 cm depth. The contribution of springs and wetlands to stream discharge increased from a median of 16.5 (95 % confidence interval: 11.3–22.9), 2.1 (−3.0–24.2) and 50.2 (30.5–65.5) % during low flow to 20.7 (15.2–34.7), 53.0 (23.0–91.3) and 69.4 (43.0–123.9) % during high flow in the natural forest, smallholder agriculture and tea plantation sub-catchments, respectively. Our results indicate that groundwater is an important component of stream water, irrespective of land use. The results further suggest that the selected transit time models and tracers might not be appropriate in tropical catchments with highly damped stream water isotope signatures. A more in-depth investigation of the discharge dependence of the young water fraction and transit time estimation using other tracers, such as tritium, could therefore shed more light on potential land use effects on the hydrological behaviour of tropical montane catchments.Item Effect of land cover and hydro-meteorological controls on soil water doc concentrations in a high-elevation tropical environment(2018) Pesántez Vallejo, Juan Patricio; Mosquera, Giovanny; Crespo Sánchez, Patricio Javier; Breuer, Lutz; Windhorst, DavidPáramo soils store high amounts of organic carbon. However, the effects of climate change and changes in land cover and use (LC/LU) in this high-elevation tropical ecosystem may cause a decrease in their carbon storage capacity. Therefore, better understanding of the factors influencing the Páramo soils' carbon storage and export is urgently needed. To fill this knowledge gap, we investigated the differences in dissolved organic carbon (DOC) content in the soil water of four LC/LU types (tussock grass, natural forest, pine plantations, and pasture) and the factors controlling its variability in the Quinuas Ecohydrological Observatory in south Ecuador. Weekly measurements of soil water DOC concentrations, meteorological variables, soil water content, and temperature from various depths and slope positions were monitored within the soils' organic and mineral horizons between October 2014 and January 2017. These data were used to generate regression trees and random forest statistical models to identify the factors controlling soil water DOC concentrations. From high to low concentrations, natural forest depict the highest DOC concentrations followed by pasture, tussock grass, and pine forest. For all LC/LU types, DOC concentrations increase with decreasing soil moisture. Our results also show that LC/LU is the most important predictor of soil water DOC concentrations, followed by sampling depth and soil moisture. Interestingly, atmospheric variables and antecedent evapotranspiration and precipitation conditions show only little influence on DOC concentrations during the monitoring period. Our findings provide unique information that can help improve the management of soil and water resources in the Páramo and other peat dominated ecosystems elsewhere. © 2018 John Wiley & Sons, Ltd.Item Global climate change impacts on local climate and hydrology(Springer, Berlin, Heidelberg, 2013) Timbe Castro, Edison PatricioGlobal climate change will most likely have a severe impact on local climate and hydrological cycling in the tropical montane rainforest. We used a simple statistical downscaling technique for eight general circulation models and two IPCC AR4 emission scenarios (A1B, A2) to forecast feasible local climate conditions for the San Francisco river basin for three future time slices (2010–2039, 2040–2069, 2070–2099). These simulations were then used as forcing data for an ensemble of seven catchment scale rainfall-runoff models to investigate the effects on local hydrological fluxes. Precipitation for both emission scenarios is expected to increase, especially in the months May and June. These increases in precipitation input will lead to even more dynamic discharges as today. However, part of the increasing water input is compensated by raising evapotranspiration due to higher temperatures. Finally, we give an outlook on feasible future trends of water-related ecosystem services under climate change.Item Identifcation of the runoff generation processes in a montane cloud forest combining hydrometric data and mixing model analysis(Universidad de Cuenca, 2011-07) Crespo Sánchez, Patricio Javier; Bücker, Amelie; Feyen, Jan; Vache, Kellie B.; Frede, Hans Georg; Universidad de Cuenca; Dirección de Investigación de la Universidad de Cuenca; Breuer, LutzField observations of runoff generation in pristine montane cloud forests are scarce. However, this knowledge is important for a sustainable natural resources management. Here we report results of a study carried out in the San Francisco River basin (75,3 km2) located on the Amazonian side of the Cordillera Real in the southernmost Andes of Ecuador. The basin is mainly covered with cloud forest, sub-páramo, pasture and ferns. A nested sampling approach was used for the collection of stream water samples and discharge measurements in the main tributaries and outlet of the basin. Additionally, soil and rock water samples were collected. Weekly to biweekly water grab samples were taken at all stations in the period April 2007 to November 2008. Hydrometric, mean residence time and mixing model approaches allowed identifying the main hydrological processes that control the runoff generation in the basin. Results clearly reveal that flow during dry conditions mainly consists of lateral flow through the C-horizon and cracks in the top weathered bedrock layer. The data shows that all catchments have an important contribution of this deep water to runoff, no matter whether pristine or deforested. During normal to low precipitation intensities, when antecedent soil moisture conditions favor water infiltration, vertical flow paths to deeper soil horizons with subsequent lateral sub-surface flow contributes most to streamflow. Under wet conditions in forested catchments streamflow is controlled by near-surface lateral flow through the organic horizon, and it is unlikely that Horton overland flow occurs during storm events. By absence of the litter layer in pasture streamflow under wet conditions primarily originates from the rooted surface layers and the A horizon, and Hortonian overland flow during extreme events.Item Identifying controls of the rainfall-runoff response of small catchments in the tropical Andes (Ecuador)(2011-07-24) Crespo, Patricio; Feyen, Jan; Buytaert, Wouter; Bücker, Amelie; Breuer, Lutz; Frede, Hans Georg; Ramírez, MarcoTropical mountain regions are characterized by strong spatial climate gradients which together with the limited amount of data and knowledge of the underlying processes hinder the management of the water resources. Especially for regional-scale prediction it is important to identify the dominant factors controlling the rainfall–runoff response and link those to known spatial patterns of climate, soils, and vegetation. This study analyzes the rainfall–runoff relation of 13 intensively monitored micro-catchments in the Andes of southern Ecuador. The results of this study show that streamflow in the southern cordillera of the Ecuadorian Andes, above 2500 m a.s.l., primarily consists of subsurface flow. The yearly amount of streamflow is controlled by the annual rainfall depth, whereas the temporal distribution is mainly governed by the lateral saturated hydraulic conductivity, the soil water retention and the antecedent soil moisture content. Anthropogenic effects were found insignificant, with the exception in one of the studied micro-catchment. Effect of land use changes in most of the micro-catchments did not reflect in the shape of the flow duration curve because either the spatial extent of human impact was small and/or the overall basin slope was less than 20%.Item Identifying controls on water chemistry of tropical cloud forest catchments: Combining descriptive approaches and multivariate analysis(2010) Bücker, Amelie; Crespo, Patricio; Frede, Hans Georg; Vaché, Kellie B.; Cisneros, Felipe; Breuer, LutzWe investigated controls on the water chemistry of a South Ecuadorian cloud forest catchment which is partly pristine, and partly converted to extensive pasture. From April 2007 to May 2008 water samples were taken weekly to biweekly at nine different subcatchments, and were screened for differences in electric conductivity, pH, anion, as well as element composition. A principal component analysis was conducted to reduce dimensionality of the data set and define major factors explaining variation in the data. Three main factors were isolated by a subset of 10 elements (Ca2?, Ce, Gd, K?, Mg2?, Na?, Nd, Rb, Sr, Y), explaining around 90% of the data variation. Land-use was the major factor controlling and changing water chemistry of the subcatchments. A second factor was associated with the concentration of rare earth elements in water, presumably highlighting other anthropogenic influences such as gravel excavation or road construction. Around 12% of the variation was explained by the third component, which was defined by the occurrence of Rb and K and represents the influence of vegetation dynamics on element accumulation and wash-out. Comparison of base- and fast flow concentrations led to the assumption that a significant portion of soil water from around 30 cm depth contributes to storm flow, as revealed by increased rare earth element concentrations in fast flow samples. Our findings demonstrate the utility of multi-tracer principal component analysis to study tropical headwater streams, and emphasize the need for effective land management in cloud forest catchments.Item Impact of elevation and weather patterns on the isotopic composition of precipitation in a tropical montane rainforest(2013) Windhorst, David; Waltz, T.; Timbe Castro, Edison Patricio; Frede, H. G.; Breuer, LutzThis study presents the spatial and temporal variability of δ18O and δ2H isotope signatures in precipitation of a south Ecuadorian montane cloud forest catchment (San Francisco catchment). From 2 September to 25 December 2010, event sampling of open rainfall was conducted along an altitudinal transect (1800 to 2800 m a.s.l.) to investigate possible effects of altitude and weather conditions on the isotope signature. The spatial variability is mainly affected by the altitude effect. The event based δ18O altitude effect for the study area averages −0.22‰ × 100 m−1 (δ2H: −1.12‰ × 100 m−1). The temporal variability is mostly controlled by prevailing air masses. Precipitation during the times of prevailing southeasterly trade winds is significantly enriched in heavy isotopes compared to precipitation during other weather conditions. In the study area, weather during austral winter is commonly controlled by southeasterly trade winds. Since the Amazon Basin contributes large amounts of recycled moisture to these air masses, trade wind-related precipitation is enriched in heavy isotopes. We used deuterium excess to further evaluate the contribution of recycled moisture to precipitation. Analogously to the δ18O and δ2H values, deuterium excess is significantly higher in trade wind-related precipitation. Consequently, it is assumed that evaporated moisture is responsible for high concentrations of heavy isotopes during austral winter.Item Land-use effects on structural and functional composition of benthic and leaf-associated macroinvertebrates in four Andean streams(2018) Iñiguez Armijos, Carlos; Hampel, Henrietta; Breuer, LutzThe replacement of native forests by pastures takes place widely in the Andes. The effects of such land-use change on aquatic assemblages are poorly understood. We conducted a comparative analysis of the effects of forest conversion to pastures on the taxonomic, structural, and functional composition of macroinvertebrates (benthic and leaf-associated) in montane and upper montane streams (ecosystem type) of the south Ecuadorian Andes. Taxonomic composition of benthic and leaf-associated macroinvertebrates was different between ecosystem type and land use. Also, major differences in the structural and functional composition of benthic and leaf-associated macroinvertebrates were mainly promoted by land use in both ecosystem types. Forested streams showed higher diversity than pasture streams, sustaining more shredder, scraper, and predatory invertebrates. We also observed differences in the macroinvertebrate communities between benthic and leaf-bag samples. Leaf bags had lower diversity and more collector invertebrates than benthic samples. This study highlights the large effect of riparian forest conversion to pasture land on macroinvertebrate communities, and the importance of using appropriate sampling techniques to characterize aquatic assemblages. We also recommend the maintenance and restoration of riparian vegetation to mitigate the effects of deforestation on stream communities and ecosystem processes.Item Model intercomparison to explore catchment functioning: results from a remote montane tropical rainforest(2012-07-24) Plesca, I.; Timbe, Edison; Exbrayat, J. F.; Windhorst, David; Kraft, P.; Crespo, P.; Vaché, Kellie B.; Frede, Hans Georg; Breuer, LutzCatchment-scale runoff generation involves a complex interaction of physical and chemical processes operating over a wide distribution of spatial and temporal scales. Understanding runoff generation is challenged by this inherent complexity – the more uncertain step of predicting the hydrologic response of catchments is that much more challenging. Many different hypotheses have been implemented in hydrological models to capture runoff generation processes and provide hydrologic predictions. These concepts have been developed based on extended field observations. Here we propose inferring water flux understanding and catchment exploring through the application of a variety of available hydrological models as a mechanism to build upon and extend models that have been developed to capture particular hydrological processes. We view this ensemble modeling strategy as particularly appropriate in ungauged catchments. The study is carried out in a tropical montane rainforest catchment in Southern Ecuador. The catchment is 75 km2 and is covered by forest in the south, while the northern slopes have been partly deforested for grazing. Annual rainfall is highly variable, reaching up to 5700 mm per year in the upper parts of the catchment. To explore the dominating runoff processes, an ensemble of 6 hydrological models with different structures applied over different levels of both spatial and temporal detail was developed. The ensemble includes spatially lumped (HBV-light), semi-distributed (HEC-HMS, CHIMP, SWAT, LASCAM) and a fully distributed model (HBV-N-D). The hydro-statistical toolkit WETSPRO was used to characterize simulated and observed hydrographs. Estimated baseflow indices, flow minima and maxima, flow duration curves and cumulative errors were generated and compared among the ensemble of models. This process facilitated the exploration of processes controlling runoff generation, enabled an evaluation of the applicability of the screened models to tropical montane rainforests, and provided the capacity to evaluate and explain where different models failed.Item Model intercomparison to explore catchment functioning: results from a remote montane tropical rainforest(2012) Plesca, Ina; Timbe Castro, Edison Patricio; Exbrayat, Jean Francois; Windhorst, David; Kraft, Philipp; Crespo Sánchez, Patricio Javier; Vaché, K. B.; Frede, Hans Georg; Breuer, LutzCatchment-scale runoff generation involves a complex interaction of physical and chemical processes operating over a wide distribution of spatial and temporal scales. Understanding runoff generation is challenged by this inherent complexity – the more uncertain step of predicting the hydrologic response of catchments is that much more challenging. Many different hypotheses have been implemented in hydrological models to capture runoff generation processes and provide hydrologic predictions. These concepts have been developed based on extended field observations. Here we propose inferring water flux understanding and catchment exploring through the application of a variety of available hydrological models as a mechanism to build upon and extend models that have been developed to capture particular hydrological processes. We view this ensemble modeling strategy as particularly appropriate in ungauged catchments. The study is carried out in a tropical montane rainforest catchment in Southern Ecuador. The catchment is 75 km2 and is covered by forest in the south, while the northern slopes have been partly deforested for grazing. Annual rainfall is highly variable, reaching up to 5700 mm per year in the upper parts of the catchment. To explore the dominating runoff processes, an ensemble of 6 hydrological models with different structures applied over different levels of both spatial and temporal detail was developed. The ensemble includes spatially lumped (HBV-light), semi-distributed (HEC-HMS, CHIMP, SWAT, LASCAM) and a fully distributed model (HBV-N-D). The hydro-statistical toolkit WETSPRO was used to characterize simulated and observed hydrographs. Estimated baseflow indices, flow minima and maxima, flow duration curves and cumulative errors were generated and compared among the ensemble of models. This process facilitated the exploration of processes controlling runoff generation, enabled an evaluation of the applicability of the screened models to tropical montane rainforests, and provided the capacity to evaluate and explain where different models failed.Item Moisture transport and seasonal variations in the stable isotopic composition of rainfall in Central American and Andean Páramo during El Niño conditions (2015-2016)(2019) Esquivel Hernández, Germain; Mosquera Rojas, Giovanny Mauricio; Sánchez Murillo, Ricardo; Quesada Román, Adolfo; Birkel, Christian; Crespo Sánchez, Patricio Javier; Célleri Alvear, Rolando Enrique; Windhorst, David; Breuer, Lutz; Boll, JanHigh‐elevation tropical grassland systems, called Páramo, provide essential ecosystem services such as water storage and supply for surrounding and lowland areas. Páramo systems are threatened by climate and land use changes. Rainfall generation processes and moisture transport pathways influencing precipitation in the Páramo are poorly understood but needed to estimate the impact of these changes, particularly during El Niño conditions which largely affect hydrometeorological conditions in tropical regions. To fill this knowledge gap, we present a stable isotope analysis of rainfall samples collected on a daily to weekly basis between January 2015 and May 2016 during the strongest El Niño event recorded in history (2014‐2016) in two Páramo regions of Central America (Chirripó, Costa Rica) and the northern Andes (Cajas, south Ecuador). Isotopic compositions were used to identify how rainfall …Item Multicriteria assessment of water dynamics reveals subcatchment variability in a seemingly homogeneous tropical cloud forest catchment(2017) Timbe Castro, Edison Patricio; Feyen, Jan; Timbe Castro, Luis Manuel; Crespo Sánchez, Patricio Javier; Célleri Alvear, Rolando Enrique; Windhorst, David; Frede, Hans Georg; Breuer, LutzTo improve the current knowledge of the rainfall–runoff phenomena of tropical montane catchments, we explored the usefulness of several hydrological indicators on a nested cloud forest catchment (76.9 km2). The used metrics belong to 5 categories: baseflow mean transit time, physicochemical properties of stream water, land cover, topographic, and hydrometric parameters. We applied diverse statistical techniques for data analysis and to contrast findings. Multiple regression analysis showed that mean transit times of base flow could be efficiently predicted by sodium concentrations (higher during baseflows) and temperatures of stream water, indicating a major influence of geomorphology rather than topographic or land cover characteristics. Principal component analysis revealed that no specific subset of catchment indicators could be identified as prevailing descriptors for all catchments. The agglomerative hierarchical clustering analysis provided concomitant results, implying larger levels of dissimilarity between smaller subcatchments than between larger ones. Overall, results point out an intricate interdependence of diverse processes at surface and subsurface level indicating a high level of heterogeneity. Disregarding heterogeneity of nested or paired catchments could lead to incomplete or misleading conclusions, especially in tropical mountain regions where pronounced spatial and temporal gradients are present.Item Preliminary evaluation of the runoff processes in a remote montane cloud forest basin using mixing model analysis and mean transit time(2012-12-15) Crespo, Patricio; Bücker, Amelie; Feyen, Jan; Vaché, Kellie B.; Frede, Hans Georg; Breuer, LutzIn this study, the Mean Transit Time and Mixing Model Analysis methods are combined to unravel the runoff generation process of the San Francisco River basin (73.5 km2) situated on the Amazonian side of the Cordillera Real in the southernmost Andes of Ecuador. The montane basin is covered with cloud forest, sub-páramo, pasture and ferns. Nested sampling was applied for the collection of streamwater samples and discharge measurements in the main tributaries and outlet of the basin, and for the collection of soil and rock water samples. Weekly to biweekly water grab samples were taken at all stations in the period April 2007–November 2008. Hydrometric data, Mean Transit Time and Mixing Model Analysis allowed preliminary evaluation of the processes controlling the runoff in the San Francisco River basin. Results suggest that flow during dry conditions mainly consists of lateral flow through the C-horizon and cracks in the top weathered bedrock layer, and that all subcatchments have an important contribution of this deep water to runoff, no matter whether pristine or deforested. During normal to low precipitation intensities, when antecedent soil moisture conditions favour water infiltration, vertical flow paths to deeper soil horizons with subsequent lateral subsurface flow contribute most to streamflow. Under wet conditions in forested catchments, streamflow is controlled by near surface lateral flow through the organic horizon. Exceptionally, saturation excess overland flow occurs. By absence of the litter layer in pasture, streamflow under wet conditions originates from the A horizon, and overland flow.Item Sampling frequency trade-offs in the assessment of mean transit times of tropical montane catchment waters under semi-steady-state conditions(2015) Timbe Castro, Edison Patricio; Windhorst, David; Célleri Alvear, Rolando Enrique; Timbe Castro, Luis Manuel; Crespo Sánchez, Patricio Javier; Frede, Hans Georg; Feyen, Jan; Breuer, LutzPrecipitation event samples and weekly based water samples from streams and soils were collected in a tropical montane cloud forest catchment for 2 years and analyzed for stable water isotopes in order to understand the effect of sampling frequency in the performance of three lumped-parameter distribution functions (exponential-piston flow, linear-piston flow and gamma) which were used to estimate mean transit times of waters. Precipitation data, used as input function for the models, were aggregated to daily, weekly, bi-weekly, monthly and bi-monthly sampling resolutions, while analyzed frequencies for outflows went from weekly to bi-monthly. By using different scenarios involving diverse sampling frequencies, this study reveals that the effect of lowering the sampling frequency depends on the water type. For soil waters, with transit times on the order of few weeks, there was a clear trend of over predictions. In contrast, the trend for stream waters, which have a more damped isotopic signal and mean transit times on the order of 2 to 4 years, was less clear and showed a dependence on the type of model used. The trade-off to coarse data resolutions could potentially lead to misleading conclusions on how water actually moves through the catchment, notwithstanding that these predictions could reach better fitting efficiencies, fewer uncertainties, errors and biases. For both water types an optimal sampling frequency seems to be 1 or at most 2 weeks. The results of our analyses provide information for the planning of future fieldwork in similar Andean or other catchments.Item Solute behaviour and export rates in neotropical montane catchments under different land-uses(2011-03-10) Bücker, Amelie; Crespo, Patricio; Frede, Hans Georg; Breuer, LutzTo improve our knowledge of the influence of land-use on solute behaviour and export rates in neotropical montane catchments we investigated total organic carbon (TOC), Ca, Mg, Na, K, NO3 and SO4 concentrations during April 2007–May 2008 at different flow conditions and over time in six forested and pasture-dominated headwaters (0.7–76 km2) in Ecuador. NO3 and SO4 concentrations decreased during the study period, with a continual decrease in NO3and an abrupt decrease in February 2008 for SO4. We attribute this to changing weather regimes connected to a weakening La Niña event. Stream Na concentration decreased in all catchments, and Mg and Ca concentration decreased in all but the forested catchments during storm flow. Under all land-uses TOC increased at high flows. The differences in solute behaviour during storm flow might be attributed to largely shallow subsurface and surface flow paths in pasture streams on the one hand, and a predominant origin of storm flow from the organic layer in the forested streams on the other hand. Nutrient export rates in the forested streams were comparable to the values found in literature for tropical streams. They amounted to 6–8 kg ha−1 y−1 for Ca, 7–8 kg ha−1 y−1 for K, 4–5 kg ha−1y−1 for Mg, 11–14 kg ha−1 y−1 for Na, 19–22 kg ha−1 y−1 for NO3 (i.e. 4.3–5.0 kg ha−1 y−1 NO3-N) and 17 kg ha−1 y−1 for SO4. Our data contradict the assumption that nutrient export increases with the loss of forest cover. For NO3we observed a positive correlation of export value and percentage forest cover.Item Spatially distributed hydro-chemical data with temporally high-resolution is needed to adequately assess the hydrological functioning of headwater catchments(2019) Correa Barahona, Alicia Beatriz; Breuer, Lutz; Crespo Sánchez, Patricio Javier; Célleri Alvear, Rolando Enrique; Feyen, Jan; Birkel, Christian; Silva Alemán, Camila Fernanda; Windhorst, DavidAbstract We demonstrated the great value of spatially distributed and temporally high-resolution hydro-chemical data to enhance knowledge about the intra-catchment variability of flow processes and the runoff composition of individual storms in a tropical alpine (Paramo) ecosystem. In this study, water sources (rainfall, spring water, and water from soil layers of Histosols and Andosols) and nested streams were sampled bi-weekly (2013–2014), including three storm high-resolution events (5–240 min). Water samples were analyzed for 14 tracers including electrical conductivity (EC) and rare earth trace elements and used as input to perform End-Member Mixing Analysis (EMMA). End-members identified for the outlet could explain the hydrological behavior of four out of the five tributaries, indicating similar hydro-geochemical processes and geomorphic features within the catchments. The runoff source contributions of the individual sub-catchments varied among (e.g. Andosols ~40% in tributaries and ~25% at the outlet) and within storm events (e.g. Histosols 15% higher in small peak discharge event), indicating a time-variable composition of streamflows. The latter was also reflected by the interaction of different sources and the chronology of flow paths in EMMA-space, evidencing a faster connectivity with hillslopes in the upper sub-catchments compared to the lower sub-catchments. We found counter-clockwise hysteresis patterns of storms in the lower catchments and clockwise hysteresis loops in the upper catchments. The latter bi-directionality can be related to lower slopes, wider riparian areas and the higher proportion of Histosols in the lower catchments compared to the upper sites.Item Stable water isotope tracing through hydrological models for disentangling runoff generation processes at the hillslope scale(2014) Windhorst, David; Timbe Castro, Edison Patricio; Kraft, Philipp; Frede, Hans Georg; Breuer, LutzHillslopes are the dominant landscape components where incoming precipitation becomes groundwater, streamflow or atmospheric water vapor. However, directly observing flux partitioning in the soil is almost impossible. Hydrological hillslope models are therefore being used to investigate the processes involved. Here we report on a modeling experiment using the Catchment Modeling Framework (CMF) where measured stable water isotopes in vertical soil profiles along a tropical mountainous grassland hillslope transect are traced through the model to resolve potential mixing processes. CMF simulates advective transport of stable water isotopes 18O and 2H based on the Richards equation within a fully distributed 2-D representation of the hillslope. The model successfully replicates the observed temporal pattern of soil water isotope profiles (R2 0.84 and Nash–Sutcliffe efficiency (NSE) 0.42). Predicted flows are in good agreement with previous studies. We highlight the importance of groundwater recharge and shallow lateral subsurface flow, accounting for 50 and 16% of the total flow leaving the system, respectively. Surface runoff is negligible despite the steep slopes in the Ecuadorian study region.Item Using the fuzzy cognitive map approach to promote nature-based solutions as a strategy to improve water quality in Ecuadorian communities(European Geosciences Union, 2022) Fonseca, KalinaAn adequate strategy for water quality improvement in developing countries must consider the economic scarcity of water, the external factors that affect its quality, and the participation of multisectoral stakeholders in water management decisions. In addition, stronger links to nature can be established through methods inspired from nature to clean the water, such as artificial floating islands (AFI). Restoration of aquatic ecosystems with AFIs occurs as water passes beneath the floating mat and the roots of macrophytes take up metals and nutrients. In this context, we utilized Fuzzy Cognitive Maps (FCMs) to identify the principal concepts that affect water quality from different perspectives: political, economic, social, technological, environmental, and legal (PESTEL). We also theoretically explore the use of AFIs combined with different policies, to find the strategy that best adapts the local water situation.Item Water transport and tracer mixing in volcanic ash soils at a tropical hillslope: A wet layered sloping sponge(2020) Mosquera Rojas, Giovanny Mauricio; Crespo Sánchez, Patricio Javier; Breuer, Lutz; Feyen Null, Jan Jozef albert; Windhorst, DavidAndosol soils formed in volcanic ash provide key hydrological services in montane environments. To unravel the subsurface water transport and tracer mixing in these soils we conducted a detailed characterization of soil properties and analyzed a 3-year data set of sub-hourly hydrometric and weekly stable isotope data collected at three locations along a steep hillslope. A weakly developed (52–61 cm depth), highly organic andic (Ah) horizon overlaying a mineral (C) horizon was identified, both showing relatively similar properties and subsurface flow dynamics along the hillslope. Soil moisture observations in the Ah horizon showed a fast responding (few hours) “rooted” layer to a depth of 15 cm, overlying a “perched” layer that remained near saturated year-round. The formation of the latter results from the high organic matter (33–42%) and clay (29–31%) content of the Ah horizon and an abrupt hydraulic conductivity reduction in this layer with respect to the rooted layer above. Isotopic signatures revealed that water resides within this soil horizon for short periods, both at the rooted (2 weeks) and perched (4 weeks) layer. A fast soil moisture reaction during rainfall events was also observed in the C horizon, with response times similar to those in the rooted layer. These results indicate that despite the perched layer, which helps sustain the water storage of the soil, a fast vertical mobilization of water through the entire soil profile occurs during rainfall events. The latter being the result of the fast transmissivity of hydraulic potentials through the porous matrix of the Andosols, as evidenced by the exponential shape of the water retention curves of the subsequent horizons. These findings demonstrate that the hydrological behavior of volcanic ash soils resembles that of a “layered sponge,” in which vertical flow paths dominate.
